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pmt neet discussion forum
saumya singh
Title: What is Isotoluene

Question:

What is Isotoluene?
List of Replies
pmt neet discussion forum
Gaurav Gautam
Re: What is Isotoluene

Answer:
21/09/2012

The isotoluenes in organic chemistry are the non-aromatic toluene isomers with an exocyclic double bond. They are of some academic interest in relation to aromaticity and isomerisation mechanisms.

The three basic isotoluenes are ortho-isotoluene or 5-methylene-1,3-cyclohexadiene (here labelled 1); para-isotoluene (2); and meta-isotoluene (3). Another structural isomer is the bicyclic compound 5-methylenebicyclo[2.2.0] hexene (4).

The o- and p-isotoluenes isomerise to toluene, a reaction driven by aromatic stabilisation. It is estimated that these compounds are 96 kJ mol-1 less stable.



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